| Name | Profession | Movie or TV appearance | Has Smoked IRL (In Real Life) | Quit |
| Aaliyah | singer | No | ||
| Caroline Aaron | actress | Yes | ||
| Silvia Abascal | actress | Yes | ||
| Tatiana Abbey | actress | Yes | ||
| Ursula Abbott | actress | Yes | ||
| Yaël Abecassis | actress | Yes | ||
| Inga Abel | actress | Yes | Yes? | |
| Maribel Abello | actress | Yes | ||
| Emma Åberg | actress | Yes | ||
| Betty Aberlin | actress | Yes? | ||
| Leslie Abramson | lawyer | Yes | Yes? | |
| Maria João Abreu | actress | Yes | ||
| Victoria Abril | actress | Yes | Yes | |
| Rotem Abuhab | actress | Yes | ||
| Candice Accola | actress | Yes | ||
| Isabel Achaval | actress | Yes | ||
| Amy Acker | actress | Yes | No? | |
| Alexandra Ackerman | actress | Yes | ||
| Leslie Ackerman | actress | Yes | ||
| Kathrin Ackermann | actress | Yes | ||
| Juana Acosta | actress | Yes | ? | |
| Amy Adams | actress | Yes | Yes? | |
| Beverly Adams | actress | Yes | ||
| Brooke Adams | actress | Yes | ? | |
| Edie Adams | actress | Yes | ||
| Enid-Raye Adams | actress | Yes | ||
| Jane Adams | actress | Yes | ||
| Joey Lauren Adams | actress | Yes | Yes | |
| Julie Adams | actress | Yes | ||
| Kristin Adams | actress | Yes | ||
| Maud Adams | actress | Yes | No? | |
| Neile Adams | actress | ?Yes? | ||
| Robyn Adamson | actress | Yes | ||
| María Adánez | actress | Yes | ||
| Dawn Addams | actress | Yes | ||
| Robyn Addison | actress | Yes | ||
| Melyssa Ade | actress | Yes | ||
| Jan Adele | actress | Yes | ||
| Alexandra Adi | actress | Yes | ||
| Isabelle Adjani | actress | Yes | No? |
